Product ID:142 FLASH NAPHTHA P/N 0430-00
MSDS Date:05/31/1996
FSC:6850
NIIN:00-637-6135
MSDS Number: CFFKD

CALUMET REFINING CO DIV OF CALUMENT INDUSTRIES INC

HC 62
PRINCETON, LA 71067
US

Emergency Phone: 318-949-2421(CHEMTREC 800-424-9300)

Info Phone: 318-949-2421

Preparer: JENNIFER HALL

Cage: 69487

HOC INDUSTRIES, INC

2609 WICHITA, KS 67219 US

Telephone: 316-838-4663

Cage: 0A9L8

SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC

CAS: 64742-88-7

Fraction By Weight: 100%

OSHA PEL 5 MG/M3 (OIL MIST)

ACGIH TLV: 5 MG/M3 (OIL MIST)

NAPHTHALENE (SARA 313) (CERCLA)

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: <0.5%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM/15 STEL; 9596

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,2,4-TRIMETHYLBENZENE (SARA 313)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: <0.5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9596

XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <0.5%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL;9596

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY &
GI TRACTS. ACUTE- MAY CAUSE IRRITATION OF EYES, SKIN, RESPIRATORY &
GI TRACTS. ACUTE ASPIRATION HAZARD. INGESTION OR INHALATION MAY
CAUSE HEADACHE, CENTRAL NERVO US SYSTEM DEPRESSION, CONVULSION,
LOSS OF CONSCIOUSNESS. CHRONIC- MAY PRODUCE SKIN & EYE IRRITATION,
DERMATITIS.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, NAUSEA,
VOMITING, DROWSINESS, CONVULSION, LOSS OF CONSCIOUSNESS, TEARNING,
BLURRED VISION, SKIN CRACKING, DERMATITIS, FATIGUE
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING SKIN
DISORDERS MAY BE MORE SUCCEPTIBLE TO THE EFFECTS FROM EXPOSURE TO
THIS PRODUCT.

First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:IMMEDIATELY
FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. SKIN: WASH WITH
SOAP & WATER. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF
NECESSA RY. ORAL:DO NOT INDUCE VOMITING EXCEPT ON ADVICE OF
COMPETENT MEDICAL PERSONNEL. IF CONSCIOUS, RINSE MOUTH WITH WATER.
KEEP PERSON WARM & QUIET. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.

Flash Point Method:TCC
Flash Point:>142F,>61C
Autoignition Temp:Autoignition Temp Text:>600F
Lower Limits:0.7%
Upper Limits:6%
Extinguishing Media:CARBON DIOXIDE, SAND, FOAM/DRY CHEMICAL. DO NOT USE
DIRECT STREAM OF WATER. WATER STREAM MAY SPREAD FIRE.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. COOL FIRE-EXPOSED CONTAINERS
WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES
OF IGNITION. VENTILATE AREA. CONTAIN AND PICK UP SPILL WITH
NON-FLAMMABLE ABSORBENT SUCH AS SAND, EARTH, VERMICULITE. GROUND
ALL HANDLING EQUIPMENTS. PREVE NT LIQUID FROM ENTERING SEWERS OR
WATERWAYS.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:STORE IN COOL, VENTILATED PLACE AWAY
FROM IGNITION SOURCES AND OXIDIZING MATERIALS. KEEP OUT OF REACH OF
CHILDREN.
Other Precautions:AVOID BREATHING VAPORS. DO NOT GET IN EYES, ON SKIN
OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR
DRINKING. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE (LIQUID AND
VAPOR) AND CAN BE DANGEROUS.

Respiratory Protection:UP TO 1000 PPM, NIOSH-APPROVED HALF MASK ORGANIC
VAPOR RESPIRATOR. UP TO 5000 PPM, FULL FACE ORGANIC VAPOR
RESPIRATOR OR SUPPLIED AIR RESPIRATOR. IN EMERGENCY/>5000, WEAR A
NIOSH-APPROVED POSITIVE-PRE SSURE SELF-CONTAINED BREATHING
APPARATUS
Ventilation:LOCAL EXHAUST IS RECOMMENDED FOR CONFINED AREAS. GENERAL
MECHANICAL VENTILATION IS ADEQUATE FOR NORMAL USE.
Protective Gloves:NEOPRENE OR NITRILE FOR REPEATED CONTACT
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE
CLOTHING
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
NOTE: INGREDIENTS 2-4 ARE FOUND ON PAGE 5, SECTION 15 OF MFR'S MSDS,
"REGULATORY INFORMATION".

HCC:V4
Boiling Pt:B.P. Text:>356F,>180C
Vapor Pres:5.2 @ 100F
Vapor Density:6
Volatile Org Content %:99
Spec Gravity:0.78
Viscosity:1.3 CST @100F
Evaporation Rate & Reference:<1 (ETHYL ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID, KEROSINE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS
Stability Condition to Avoid:OPEN FLAME AND EXTREME HEAT
Hazardous Decomposition Products:MAY FORM SMOKE, CARBON MONOXIDE,
CARBON DIOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. INCINERATION OR RECYCLING IS RECOMMENDED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.